Science-2011-Dong-1609-12.pdf
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PrimaryAlcoholsfromTerminalOlefins:FormalAnti-MarkovnikovHydrationviaTripleRelayCatalysisGuangbinDongetal.Science333,1609(2011);DOI:10.1126/science.1208685Thiscopyisforyourpersonal,non-commercialuseonly.Ifyouwishtodistributethisarticletoothers,youcanorderhigh-qualitycopiesforyourcolleagues,clients,orcustomersbyclickinghere.Permissiontorepublishorrepurposearticlesorportionsofarticlescanbeobtainedbyfollowingtheguidelineshere.Thefollowingresourcesrelatedtothisarticleareavailableonlineatwww.sciencemag.org(thisinformationiscurrentasofNovember23,2012):Updatedinformationandservices,includinghigh-resolutionfigures,canbefoundintheonlineversionofthisarticleat:onNovember23,2012http://www.sciencemag.org/content/333/6049/1609.full.htmlSupportingOnlineMaterialcanbefoundat:http://www.sciencemag.org/content/suppl/2011/09/14/333.6049.1609.DC1.htmlAlistofselectedadditionalarticlesontheScienceWebsitesrelatedtothisarticlecanbefoundat:http://www.sciencemag.org/content/333/6049/1609.full.html#relatedThisarticlecites35articles,1ofwhichcanbeaccessedfree:http://www.sciencemag.org/content/333/6049/1609.full.html#ref-list-1www.sciencemag.orgThisarticleappearsinthefollowingsubjectcollections:Chemistryhttp://www.sciencemag.org/cgi/collection/chemistryDownloadedfromScience(printISSN0036-8075;onlineISSN1095-9203)ispublishedweekly,exceptthelastweekinDecember,bytheAmericanAssociationfortheAdvancementofScience,1200NewYorkAvenueNW,Washington,DC20005.Copyright2011bytheAmericanAssociationfortheAdvancementofScience;allrightsreserved.ThetitleScienceisaregisteredtrademarkofAAAS.REPORTSdemonstratethereproducibilityofthesehighlyreactivityundertheinfluenceofexogenous17.J.M.Lenhardt,A.L.Black,S.L.Craig,J.Am.Chem.Soc.efficientprocesses,TriPwassuccessfullysub-mechanicalforces.131,10818(2009).16018.K.M.Wigginsetal.,J.Am.Chem.Soc.132,3256jectedtotwocyclesofmechanicallyinduced(2010).cycloreversionandsubsequentCucatalyzedReferencesandNotes19.J.Ribas-Arino,M.Shiga,D.Mar