chapter 14 Structure and Synthesis of Alcohols.ppt
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chapter 14 Structure and Synthesis of Alcohols.ppt

chapter14StructureandSynthesisofAlcohols.ppt

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Chapter14StructureandSynthesisofAlcoholsStructureofAlcoholsClassificationClassifythese:IUPACNomenclatureNamethese:UnsaturatedAlcoholsNamingPriorityHydroxySubstituentCommonNamesNamingDiolsGlycolsNamingPhenolsPhysicalPropertiesBoilingPointsSolubilityinWaterMethanolEthanol2-PropanolAcidityofAlcoholsTableofKaValuesFormationofAlkoxideIonsFormationofPhenoxideIonSynthesis(Review)Glycols(Review)OrganometallicReagentsGrignardReagentsSomeGrignardReagentsOrganolithiumReagentsReactionwithCarbonylSynthesisof1°AlcoholsSynthesisof2ºAlcoholsSynthesisof3ºAlcoholsHowwouldyousynthesize…GrignardReactionswithAcidChloridesandEstersGrignard+AcidChloride(1)GrignardandEster(1)SecondstepofreactionHowwouldyousynthesize...GrignardReagent+EthyleneOxideLimitationsofGrignardReductionofCarbonylSodiumBorohydrideLithiumAluminumHydrideComparisonofReducingAgentsCatalyticHydrogenationThiols(Mercaptans)ThiolSynthesisThiolOxidationEndofChapter10