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Occurrence,Biogenesis,andSynthesisofBiologicallyActiveCarbazoleAlkaloidsArndtW.Schmidt,KethiriR.Reddy,andHans-JoachimKno?lker*DepartmentChemie,TechnischeUniversita?tDresden,Bergstrasse66,01069Dresden,GermanyCONTENTS1.IntroductionB1.1.GeneralB1.2.SyntheticMethodsforCarbazolesC1.2.1.Fischer?BorscheSynthesisC1.2.2.Graebe?UllmannSynthesisC1.2.3.CyclizationofBiarylnitrenesCadoganSynthesisC1.2.4.ElectrocyclicReactionstoCarbazolesD1.2.5.Iron-MediatedCarbazoleSynthesisD1.2.6.Palladium-CatalyzedCyclizationstoCar-bazolesE1.2.7.MiscellaneousMethodsF2.BiogenesisofCarbazoleAlkaloidsG3.TricyclicCarbazoleAlkaloidsN3.1.Carbazole,3-Methylcarbazole,andNon-Oxy-genatedCongenersO3.1.1.IsolationfromNaturalSourcesO3.1.2.Synthesisof3-Methylcarbazole,9-Car-bethoxy-3-methylcarbazole,9-Formyl-3-methylcarbazoleO3.1.3.SynthesesofMethylCarbazole-3-car-boxylateO3.1.4.Palladium(0)-CatalyzedSynthesesofCarbazoleP3.1.5.SynthesisofCarbazolebyPhotoiniti-atedCyclizationP3.1.6.SynthesesofCarbazole,3-Methylcarba-zole,andMethylCarbazole-3-carboxy-lateviaBenzyneQ3.1.7.SynthesesofCarbazolefromBiarylPrecursorsQ3.1.8.Palladium(0)-CatalyzedSynthesisofCar-bazole,3-Methylcarbazole,andMethylCarbazole-3-carboxylateR3.1.9.SynthesesofHalogenatedCarbazolesR3.2.MonooxygenatedCarbazoleAlkaloidsS3.2.1.1-OxygenatedCarbazoleAlkaloidsS3.2.2.2-OxygenatedCarbazoleAlkaloidsW3.2.3.3-OxygenatedCarbazoleAlkaloidsAA3.2.4.5-OxygenatedCarbazoleAlkaloidsAG3.2.5.6-OxygenatedCarbazoleAlkaloidsAH3.2.6.7-OxygenatedCarbazoleAlkaloidsAK3.2.7.8-OxygenatedCarbazoleAlkaloidsAM3.2.8.9-OxygenatedCarbazoleAlkaloidsAM3.3.DioxygenatedCarbazoleAlkaloidsAN3.3.1.1,6-DioxygenatedCarbazoleAlkaloidsAN3.3.2.1,7-DioxygenatedCarbazoleAlkaloidsAQ3.3.3.1,8-DioxygenatedCarbazoleAlkaloidsAQ3.3.4.2,5-DioxygenatedCarbazoleAlkaloidsAR3.3.5.2,6-DioxygenatedCarbazoleAlkaloidsAR3.3.6.2,7-DioxygenatedCarbazoleAlkaloidsAS3.3.7.2,8-DioxygenatedCarbazoleAlkal
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