IntroductionExperimentMaterialsPreparationofsamplesMeasurementResultsanddiscussionConclusionsSincethelastcentury,plasticindustryhasdevelopedsofastthatplasticproductshavegaineduniversalapplicationinmanyfields.However,mostoftheplasticproductsarenotbiodegradable,andthiscausesseriousenvironmentalpollution.Amongaliphaticpolyesters,poly(butylenesuccinate)(PBS)hasrelativelyhighermeltingtemperatureandotherexcellentproperties.However,theinsufficientmechanicalpropertiesofPBShavepreventeditfrombeingusedindiverseapplications.CrosslinkingisanothereffectivemethodtoimprovethepropertiesofPBS.Materials(1/2)Poly(butylenesuccinate)(聚琥珀酸丁酯，PBS)Montmorillonite(奈米蒙脫土，MMT)(HT：hydrogenatedTallow)Materials(2/2)DicumylPeroxide(過氧化二異丙苯，DCP)Triallylisocyanurate(三烯丙基異三聚氰酸酯，TAIC)Preparationofsamples1.ModificationofMontmorillonite2.PreparationofsamplesPBSMechanismTable1ThecompositionandcodeofsamplesMeasurementThermalGravimetricAnalyzer(熱重分析儀，TGA)DifferentialScanningCalorimeter(微差掃描式熱分析儀，DSC)PolarizingOpticalMicroscope(偏光顯微鏡，POM)GelfractionofcrosslinkedPBS(交聯程度測試)Biodegradability(生物分解性實驗)Waterabsorption(吸水性實驗)Table2ThesamplesofgelfractionTGAanalysisDSCanalysisPOMobservationPOMobservationBiodegradationofcrosslinkedPBSWaterabsorptiontest1.ThemodifiedmontmorillonitecanenhancethethermalstabilityofPBS.2.Gelfractionincreasedwithincreasingcontentofthecrosslinkingagent.3.Ascrosslinkedhappened,Tcshiftedtohighertemperatures,andthedegreeofcrystallinitydecreasedslightly.4.ThedegradationrateofPBSwasdecreasedwiththeintroductionofcrosslinkedstructure.5.Inwaterabsorptiontesting,theresultsrevealthatPBSisahydrophobicmaterialandthemontmorillonite-containingsampletendstobeahydrophilicmaterial.19利用索氏萃取(Soxhletextraction)裝置，取適量交聯後之PBS樣品，並秤其重量We使用氯仿為溶劑，於80℃下，萃取24小時，將樣品中未交聯之分子洗去，再將交聯之樣品烘乾之後秤重Wf，即可計算其交聯度(Gelfraction)。先將試片，各別秤重記錄初始重量Wa，放入樣品瓶中，加入含有酵素之緩衝溶液中，於往復式震盪恆溫水槽中，於50℃下，轉速175rpm下震盪。每48小時將樣品